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72 FR 32717, June 13, 2007, unless otherwise noted. (a) The affected facilities to which the provisions of this subpart apply are: (1) Each fossil-fuel-fired steam generating unit of more than 73 megawatts (MW) heat input rate (250 million British thermal units per hour (MMBtu/hr)). (2) Each fossil-fuel and wood-residue-fired steam generating unit capable of firing fossil fuel at a heat input rate of more than 73 MW (250 MMBtu/hr). (b) Any change to an existing fossil-fuel-fired steam generating unit to accommodate the use of combustible materials, other than fossil fuels as defined in this subpart, shall not bring that unit under the applicability of this subpart. (c) Except as provided in paragraph (d) of this section, any facility under paragraph (a) of this section that commenced construction or modification after August 17, 1971, is subject to the requirements of this subpart. (d) The requirements of §§60.44 (a)(4), (a)(5), (b) and (d), and 60.45(f)(4)(vi) are applicable to lignite-fired steam generating units that commenced construction or modification after December 22, 1976. (e) Any facility covered under subpart Da is not covered under this subpart. § 60.41 Definitions.As used in this subpart, all terms not defined herein shall have the meaning given them in the Act, and in subpart A of this part. Boiler operating day means a 24-hour period between 12 midnight and the following midnight during which any fuel is combusted at any time in the steam-generating unit. It is not necessary for fuel to be combusted the entire 24-hour period. Coal means all solid fuels classified as anthracite, bituminous, subbituminous, or lignite by ASTM D388 (incorporated by reference, see §60.17). Coal refuse means waste-products of coal mining, cleaning, and coal preparation operations (e.g. culm, gob, etc.) containing coal, matrix material, clay, and other organic and inorganic material. Fossil fuel means natural gas, petroleum, coal, and any form of solid, liquid, or gaseous fuel derived from such materials for the purpose of creating useful heat. Fossil fuel and wood residue-fired steam generating unit means a furnace or boiler used in the process of burning fossil fuel and wood residue for the purpose of producing steam by heat transfer. Fossil-fuel-fired steam generating unit means a furnace or boiler used in the process of burning fossil fuel for the purpose of producing steam by heat transfer. Wood residue means bark, sawdust, slabs, chips, shavings, mill trim, and other wood products derived from wood processing and forest management operations. § 60.42 Standard for particulate matter (PM).(a) On and after the date on which the performance test required to be conducted by §60.8 is completed, no owner or operator subject to the provisions of this subpart shall cause to be discharged into the atmosphere from any affected facility any gases that: (1) Contain PM in excess of 43 nanograms per joule (ng/J) heat input (0.10 lb/MMBtu) derived from fossil fuel or fossil fuel and wood residue. (2) Exhibit greater than 20 percent opacity except for one six-minute period per hour of not more than 27 percent opacity. (b)(1) On or after December 28, 1979, no owner or operator shall cause to be discharged into the atmosphere from the Southwestern Public Service Company's Harrington Station #1, in Amarillo, TX, any gases which exhibit greater than 35 percent opacity, except that a maximum or 42 percent opacity shall be permitted for not more than 6 minutes in any hour. (2) Interstate Power Company shall not cause to be discharged into the atmosphere from its Lansing Station Unit No. 4 in Lansing, IA, any gases which exhibit greater than 32 percent opacity, except that a maximum of 39 percent opacity shall be permitted for not more than six minutes in any hour. (c) As an alternate to meeting the requirements of paragraph (a) of this section, an owner or operator that elects to install, calibrate, maintain, and operate a continuous emissions monitoring systems (CEMS) for measuring PM emissions can petition the Administrator (in writing) to comply with §60.42Da(a) of subpart Da of this part. If the Administrator grants the petition, the source will from then on (unless the unit is modified or reconstructed in the future) have to comply with the requirements in §60.43Da(a) of subpart Da of this part. [60 FR 65415, Dec. 19, 1995, as amended at 74 FR 5077, Jan. 28, 2009] § 60.43 Standard for sulfur dioxide (SO2).(a) Except as provided under paragraph (d) of this section, on and after the date on which the performance test required to be conducted by §60.8 is completed, no owner or operator subject to the provisions of this subpart shall cause to be discharged into the atmosphere from any affected facility any gases that contain SO2in excess of: (1) 340 ng/J heat input (0.80 lb/MMBtu) derived from liquid fossil fuel or liquid fossil fuel and wood residue. (2) 520 ng/J heat input (1.2 lb/MMBtu) derived from solid fossil fuel or solid fossil fuel and wood residue, except as provided in paragraph (e) of this section. (b) Except as provided under paragraph (d) of this section, when different fossil fuels are burned simultaneously in any combination, the applicable standard (in ng/J) shall be determined by proration using the following formula: Where: PSSO y = Percentage of total heat input derived from liquid fossil fuel; and z = Percentage of total heat input derived from solid fossil fuel. (c) Compliance shall be based on the total heat input from all fossil fuels burned, including gaseous fuels. (d) As an alternate to meeting the requirements of paragraphs (a) and (b) of this section, an owner or operator can petition the Administrator (in writing) to comply with §60.43Da(i)(3) of subpart Da of this part or comply with §60.42b(k)(4) of subpart Db of this part, as applicable to the affected source. If the Administrator grants the petition, the source will from then on (unless the unit is modified or reconstructed in the future) have to comply with the requirements in §60.43Da(i)(3) of subpart Da of this part or §60.42b(k)(4) of subpart Db of this part, as applicable to the affected source. (e) Units 1 and 2 (as defined in appendix G of this part) at the Newton Power Station owned or operated by the Central Illinois Public Service Company will be in compliance with paragraph (a)(2) of this section if Unit 1 and Unit 2 individually comply with paragraph (a)(2) of this section or if the combined emission rate from Units 1 and 2 does not exceed 470 ng/J (1.1 lb/MMBtu) combined heat input to Units 1 and 2. [60 FR 65415, Dec. 19, 1995, as amended at 74 FR 5077, Jan. 28, 2009] § 60.44 Standard for nitrogen oxides (NO |
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| Fossil fuel | In parts per million | |
|---|---|---|
| Span value for SO2 | Span value for NOX | |
| Gas | (1) | 500. |
| Liquid | 1,000 | 500. |
| Solid | 1,500 | 1,000. |
| Combinations | 1,000y + 1,500z | 500 (x + y) + 1,000z. |
1Not applicable.
Where: x = Fraction of total heat input derived from gaseous fossil fuel; y = Fraction of total heat input derived from liquid fossil fuel; and z = Fraction of total heat input derived from solid fossil fuel.
(ii) As an alternative to meeting the requirements of paragraph (c)(3)(i) of this section, the owner or operator of an affected facility may elect to use the SO2and NOXspan values determined according to sections 2.1.1 and 2.1.2 in appendix A to part 75 of this chapter.
(4) All span values computed under paragraph (c)(3)(i) of this section for burning combinations of fossil fuels shall be rounded to the nearest 500 ppm. Span values that are computed under paragraph (c)(3)(ii) of this section shall be rounded off according to the applicable procedures in section 2 of appendix A to part 75 of this chapter.
(5) For a fossil-fuel-fired steam generator that simultaneously burns fossil fuel and nonfossil fuel, the span value of all CEMS shall be subject to the Administrator's approval.
(d) [Reserved]
(e) For any CEMS installed under paragraph (a) of this section, the following conversion procedures shall be used to convert the continuous monitoring data into units of the applicable standards (ng/J, lb/MMBtu):
(1) When a CEMS for measuring O2is selected, the measurement of the pollutant concentration and O2concentration shall each be on a consistent basis (wet or dry). Alternative procedures approved by the Administrator shall be used when measurements are on a wet basis. When measurements are on a dry basis, the following conversion procedure shall be used:
Where E, C, F, and %O2are determined under paragraph (f) of this section.
(2) When a CEMS for measuring CO2is selected, the measurement of the pollutant concentration and CO2concentration shall each be on a consistent basis (wet or dry) and the following conversion procedure shall be used:
Where E, C, Fcand %CO2are determined under paragraph (f) of this section.
(f) The values used in the equations under paragraphs (e)(1) and (2) of this section are derived as follows:
(1) E = pollutant emissions, ng/J (lb/MMBtu).
(2) C = pollutant concentration, ng/dscm (lb/dscf), determined by multiplying the average concentration (ppm) for each one-hour period by 4.15 × 104 M ng/dscm per ppm (2.59 × 10−9M lb/dscf per ppm) where M = pollutant molecular weight, g/g-mole (lb/lb-mole). M = 64.07 for SO2and 46.01 for NOX.
(3) %O2, %CO2= O2or CO2volume (expressed as percent), determined with equipment specified under paragraph (a) of this section.
(4) F, Fc= a factor representing a ratio of the volume of dry flue gases generated to the calorific value of the fuel combusted (F), and a factor representing a ratio of the volume of CO2generated to the calorific value of the fuel combusted (Fc), respectively. Values of F and Fcare given as follows:
(i) For anthracite coal as classified according to ASTM D388 (incorporated by reference, see §60.17), F = 2,723 × 10−17dscm/J (10,140 dscf/MMBtu) and Fc= 0.532 × 10−17scm CO2/J (1,980 scf CO2/MMBtu).
(ii) For subbituminous and bituminous coal as classified according to ASTM D388 (incorporated by reference, see §60.17), F = 2.637 × 10−7dscm/J (9,820 dscf/MMBtu) and Fc= 0.486 × 10−7scm CO2/J (1,810 scf CO2/MMBtu).
(iii) For liquid fossil fuels including crude, residual, and distillate oils, F = 2.476 × 10−7dscm/J (9,220 dscf/MMBtu) and Fc= 0.384 × 10−7scm CO2/J (1,430 scf CO2/MMBtu).
(iv) For gaseous fossil fuels, F = 2.347 × 10−7dscm/J (8,740 dscf/MMBtu). For natural gas, propane, and butane fuels, Fc= 0.279 × 10−7scm CO2/J (1,040 scf CO2/MMBtu) for natural gas, 0.322 × 10−7scm CO2/J (1,200 scf CO2/MMBtu) for propane, and 0.338 × 10−7scm CO2/J (1,260 scf CO2/MMBtu) for butane.
(v) For bark F = 2.589 × 10−7dscm/J (9,640 dscf/MMBtu) and Fc= 0.500 × 10−7scm CO2/J (1,840 scf CO2/MMBtu). For wood residue other than bark F = 2.492 × 10−7dscm/J (9,280 dscf/MMBtu) and Fc= 0.494 × 10−7scm CO2/J (1,860 scf CO2/MMBtu).
(vi) For lignite coal as classified according to ASTM D388 (incorporated by reference, see §60.17), F = 2.659 × 10−7dscm/J (9,900 dscf/MMBtu) and Fc= 0.516 × 10−7scm CO2/J (1,920 scf CO2/MMBtu).
(5) The owner or operator may use the following equation to determine an F factor (dscm/J or dscf/MMBtu) on a dry basis (if it is desired to calculate F on a wet basis, consult the Administrator) or Fc factor (scm CO2/J, or scf CO2/MMBtu) on either basis in lieu of the F or Fcfactors specified in paragraph (f)(4) of this section:
(i) %H, %C, %S, %N, and %O are content by weight of hydrogen, carbon, sulfur, nitrogen, and O2(expressed as percent), respectively, as determined on the same basis as GCV by ultimate analysis of the fuel fired, using ASTM D3178 or D3176 (solid fuels), or computed from results using ASTM D1137, D1945, or D1946 (gaseous fuels) as applicable. (These five methods are incorporated by reference, see §60.17.)
(ii) GVC is the gross calorific value (kJ/kg, Btu/lb) of the fuel combusted determined by the ASTM test methods D2015 or D5865 for solid fuels and D1826 for gaseous fuels as applicable. (These three methods are incorporated by reference, see §60.17.)
(iii) For affected facilities which fire both fossil fuels and nonfossil fuels, the F or Fc value shall be subject to the Administrator's approval.
(6) For affected facilities firing combinations of fossil fuels or fossil fuels and wood residue, the F or Fc factors determined by paragraphs (f)(4) or (f)(5) of this section shall be prorated in accordance with the applicable formula as follows:
Where: Xi= Fraction of total heat input derived from each type of fuel (e.g. natural gas, bituminous coal, wood residue, etc.); Fior (Fc)i= Applicable F or Fcfactor for each fuel type determined in accordance with paragraphs (f)(4) and (f)(5) of this section; and n = Number of fuels being burned in combination.
(g) Excess emission and monitoring system performance reports shall be submitted to the Administrator semiannually for each six-month period in the calendar year. All semiannual reports shall be postmarked by the 30th day following the end of each six-month period. Each excess emission and MSP report shall include the information required in §60.7(c). Periods of excess emissions and monitoring systems (MS) downtime that shall be reported are defined as follows:
(1) Opacity . Excess emissions are defined as any six-minute period during which the average opacity of emissions exceeds 20 percent opacity, except that one six-minute average per hour of up to 27 percent opacity need not be reported.
(i) For sources subject to the opacity standard of §60.42(b)(1), excess emissions are defined as any six-minute period during which the average opacity of emissions exceeds 35 percent opacity, except that one six-minute average per hour of up to 42 percent opacity need not be reported.
(ii) For sources subject to the opacity standard of §60.42(b)(2), excess emissions are defined as any six-minute period during which the average opacity of emissions exceeds 32 percent opacity, except that one six-minute average per hour of up to 39 percent opacity need not be reported.
(2) Sulfur dioxide. Excess emissions for affected facilities are defined as:
(i) For affected facilities electing not to comply with §60.43(d), any three-hour period during which the average emissions (arithmetic average of three contiguous one-hour periods) of SO2as measured by a CEMS exceed the applicable standard in §60.43; or
(ii) For affected facilities electing to comply with §60.43(d), any 30 operating day period during which the average emissions (arithmetic average of all one-hour periods during the 30 operating days) of SO2as measured by a CEMS exceed the applicable standard in §60.43. Facilities complying with the 30-day SO2standard shall use the most current associated SO2compliance and monitoring requirements in §§60.48Da and 60.49Da of subpart Da of this part or §§60.45b and 60.47b of subpart Db of this part, as applicable.
(3) Nitrogen oxides. Excess emissions for affected facilities using a CEMS for measuring NOXare defined as:
(i) For affected facilities electing not to comply with §60.44(e), any three-hour period during which the average emissions (arithmetic average of three contiguous one-hour periods) exceed the applicable standards in §60.44; or
(ii) For affected facilities electing to comply with §60.44(e), any 30 operating day period during which the average emissions (arithmetic average of all one-hour periods during the 30 operating days) of NOXas measured by a CEMS exceed the applicable standard in §60.44. Facilities complying with the 30-day NOXstandard shall use the most current associated NOXcompliance and monitoring requirements in §§60.48Da and 60.49Da of subpart Da of this part.
(4) Particulate matter. Excess emissions for affected facilities using a CEMS for measuring PM are defined as any boiler operating day period during which the average emissions (arithmetic average of all operating one-hour periods) exceed the applicable standards in §60.42. Affected facilities using PM CEMS must follow the most current applicable compliance and monitoring provisions in §§60.48Da and 60.49Da of subpart Da of this part.
(h) The owner or operator of an affected facility subject to the opacity limits in §60.42 that elects to monitor emissions according to the requirements in §60.45(b)(7) shall maintain records according to the requirements specified in paragraphs (h)(1) through (3) of this section, as applicable to the visible emissions monitoring method used.
(1) For each performance test conducted using Method 9 of appendix A–4 of this part, the owner or operator shall keep the records including the information specified in paragraphs (h)(1)(i) through (iii) of this section.
(i) Dates and time intervals of all opacity observation periods;
(ii) Name, affiliation, and copy of current visible emission reading certification for each visible emission observer participating in the performance test; and
(iii) Copies of all visible emission observer opacity field data sheets;
(2) For each performance test conducted using Method 22 of appendix A–4 of this part, the owner or operator shall keep the records including the information specified in paragraphs (h)(2)(i) through (iv) of this section.
(i) Dates and time intervals of all visible emissions observation periods;
(ii) Name and affiliation for each visible emission observer participating in the performance test;
(iii) Copies of all visible emission observer opacity field data sheets; and
(iv) Documentation of any adjustments made and the time the adjustments were completed to the affected facility operation by the owner or operator to demonstrate compliance with the applicable monitoring requirements.
(3) For each digital opacity compliance system, the owner or operator shall maintain records and submit reports according to the requirements specified in the site-specific monitoring plan approved by the Administrator.
[60 FR 65415, Dec. 19, 1995, as amended at 74 FR 5077, Jan. 28, 2009]
(a) In conducting the performance tests required in §60.8, and subsequent performance tests as requested by the EPA Administrator, the owner or operator shall use as reference methods and procedures the test methods in appendix A of this part or other methods and procedures as specified in this section, except as provided in §60.8(b). Acceptable alternative methods and procedures are given in paragraph (d) of this section.
(b) The owner or operator shall determine compliance with the PM, SO2, and NOXstandards in §§60.42, 60.43, and 60.44 as follows:
(1) The emission rate (E) of PM, SO2, or NOXshall be computed for each run using the following equation:
Where: E = Emission rate of pollutant, ng/J (1b/million Btu); C = Concentration of pollutant, ng/dscm (1b/dscf); %O2= O2concentration, percent dry basis; and Fd= Factor as determined from Method 19 of appendix A of this part.
(2) Method 5 of appendix A of this part shall be used to determine the PM concentration (C) at affected facilities without wet flue-gas-desulfurization (FGD) systems and Method 5B of appendix A of this part shall be used to determine the PM concentration (C) after FGD systems.
(i) The sampling time and sample volume for each run shall be at least 60 minutes and 0.85 dscm (30 dscf). The probe and filter holder heating systems in the sampling train shall be set to provide an average gas temperature of 160±14 °C (320±25 °F).
(ii) The emission rate correction factor, integrated or grab sampling and analysis procedure of Method 3B of appendix A of this part shall be used to determine the O2concentration (%O2). The O2sample shall be obtained simultaneously with, and at the same traverse points as, the particulate sample. If the grab sampling procedure is used, the O2concentration for the run shall be the arithmetic mean of the sample O2concentrations at all traverse points.
(iii) If the particulate run has more than 12 traverse points, the O2traverse points may be reduced to 12 provided that Method 1 of appendix A of this part is used to locate the 12 O2traverse points.
(3) Method 9 of appendix A of this part and the procedures in §60.11 shall be used to determine opacity.
(4) Method 6 of appendix A of this part shall be used to determine the SO2concentration.
(i) The sampling site shall be the same as that selected for the particulate sample. The sampling location in the duct shall be at the centroid of the cross section or at a point no closer to the walls than 1 m (3.28 ft). The sampling time and sample volume for each sample run shall be at least 20 minutes and 0.020 dscm (0.71 dscf). Two samples shall be taken during a 1-hour period, with each sample taken within a 30-minute interval.
(ii) The emission rate correction factor, integrated sampling and analysis procedure of Method 3B of appendix A of this part shall be used to determine the O2concentration (%O2). The O2sample shall be taken simultaneously with, and at the same point as, the SO2sample. The SO2emission rate shall be computed for each pair of SO2and O2samples. The SO2emission rate (E) for each run shall be the arithmetic mean of the results of the two pairs of samples.
(5) Method 7 of appendix A of this part shall be used to determine the NOXconcentration.
(i) The sampling site and location shall be the same as for the SO2sample. Each run shall consist of four grab samples, with each sample taken at about 15-minute intervals.
(ii) For each NOXsample, the emission rate correction factor, grab sampling and analysis procedure of Method 3B of appendix A of this part shall be used to determine the O2concentration (%O2). The sample shall be taken simultaneously with, and at the same point as, the NOXsample.
(iii) The NOXemission rate shall be computed for each pair of NOXand O2samples. The NOXemission rate (E) for each run shall be the arithmetic mean of the results of the four pairs of samples.
(c) When combinations of fossil fuels or fossil fuel and wood residue are fired, the owner or operator (in order to compute the prorated standard as shown in §§60.43(b) and 60.44(b)) shall determine the percentage (w, x, y, or z) of the total heat input derived from each type of fuel as follows:
(1) The heat input rate of each fuel shall be determined by multiplying the gross calorific value of each fuel fired by the rate of each fuel burned.
(2) ASTM Methods D2015, or D5865 (solid fuels), D240 (liquid fuels), or D1826 (gaseous fuels) (all of these methods are incorporated by reference, see §60.17) shall be used to determine the gross calorific values of the fuels. The method used to determine the calorific value of wood residue must be approved by the Administrator.
(3) Suitable methods shall be used to determine the rate of each fuel burned during each test period, and a material balance over the steam generating system shall be used to confirm the rate.
(d) The owner or operator may use the following as alternatives to the reference methods and procedures in this section or in other sections as specified:
(1) The emission rate (E) of PM, SO2and NOXmay be determined by using the Fc factor, provided that the following procedure is used:
(i) The emission rate (E) shall be computed using the following equation:
Where: E = Emission rate of pollutant, ng/J (lb/MMBtu); C = Concentration of pollutant, ng/dscm (lb/dscf); %CO2= CO2concentration, percent dry basis; and Fc= Factor as determined in appropriate sections of Method 19 of appendix A of this part.
(ii) If and only if the average Fc factor in Method 19 of appendix A of this part is used to calculate E and either E is from 0.97 to 1.00 of the emission standard or the relative accuracy of a continuous emission monitoring system is from 17 to 20 percent, then three runs of Method 3B of appendix A of this part shall be used to determine the O2and CO2concentration according to the procedures in paragraph (b)(2)(ii), (4)(ii), or (5)(ii) of this section. Then if Fo(average of three runs), as calculated from the equation in Method 3B of appendix A of this part, is more than ±3 percent than the average Fovalue, as determined from the average values of Fdand Fcin Method 19 of appendix A of this part, i.e. , Foa= 0.209 (Fda/Fca), then the following procedure shall be followed:
(A) When Fois less than 0.97 Foa, then E shall be increased by that proportion under 0.97 Foa, e.g. , if Fois 0.95 Foa, E shall be increased by 2 percent. This recalculated value shall be used to determine compliance with the emission standard.
(B) When Fois less than 0.97 Foaand when the average difference (d) between the continuous monitor minus the reference methods is negative, then E shall be increased by that proportion under 0.97 Foa, e.g. , if Fois 0.95 Foa, E shall be increased by 2 percent. This recalculated value shall be used to determine compliance with the relative accuracy specification.
(C) When Fois greater than 1.03 Foaand when the average difference d is positive, then E shall be decreased by that proportion over 1.03 Foa, e.g. , if Fois 1.05 Foa, E shall be decreased by 2 percent. This recalculated value shall be used to determine compliance with the relative accuracy specification.
(2) For Method 5 or 5B of appendix A–3 of this part, Method 17 of appendix A–6 of this part may be used at facilities with or without wet FGD systems if the stack gas temperature at the sampling location does not exceed an average temperature of 160 °C (320 °F). The procedures of sections 8.1 and 11.1 of Method 5B of appendix A–3 of this part may be used with Method 17 of appendix A–6 of this part only if it is used after wet FGD systems. Method 17 of appendix A–6 of this part shall not be used after wet FGD systems if the effluent gas is saturated or laden with water droplets.
(3) Particulate matter and SO2may be determined simultaneously with the Method 5 of appendix A of this part train provided that the following changes are made:
(i) The filter and impinger apparatus in sections 2.1.5 and 2.1.6 of Method 8 of appendix A of this part is used in place of the condenser (section 2.1.7) of Method 5 of appendix A of this part.
(ii) All applicable procedures in Method 8 of appendix A of this part for the determination of SO2(including moisture) are used:
(4) For Method 6 of appendix A of this part, Method 6C of appendix A of this part may be used. Method 6A of appendix A of this part may also be used whenever Methods 6 and 3B of appendix A of this part data are specified to determine the SO2emission rate, under the conditions in paragraph (d)(1) of this section.
(5) For Method 7 of appendix A of this part, Method 7A, 7C, 7D, or 7E of appendix A of this part may be used. If Method 7C, 7D, or 7E of appendix A of this part is used, the sampling time for each run shall be at least 1 hour and the integrated sampling approach shall be used to determine the O2concentration (%O2) for the emission rate correction factor.
(6) For Method 3 of appendix A of this part, Method 3A or 3B of appendix A of this part may be used.
(7) For Method 3B of appendix A of this part, Method 3A of appendix A of this part may be used.
[60 FR 65415, Dec. 19, 1995, as amended at 74 FR 5078, Jan. 28, 2009]
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